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"Selectivity Considerations in the Amine Extraction of Gold from Alkaline Cyanide Solutions", Minerals and Mineral Processing, pp. 153-157, 1984 Mooiman, M.B. and Pratt, J.M. "Reaction of H 2 with [CoII (CN) 5 ] 3- Ions in Aqueous Solution: The Role of Ion Pairs".
When the gold concentration is lower than 3 g L −1 and the volume percentage of TBP is less than 10%, the plots of the extraction percentage of gold against the molar ratio of [TDMBA +] to [Au(CN) 2 −] and logD–log[TBP] (o) plot indicated that the stoichiometry of the extracted species is a 1 ∶ 1 ∶ 4 complex, TDMBA + ∶ Au(CN) 2 − ...
Solvent extraction of metals and cyanide from waste cyanide solution with the guanidine extractant LIX7950 has been investigated.Gold and copper can be effectively extracted from alkaline cyanide solutions by the extractant.High cyanide levels tend to depress extraction of copper,but exhibit insignificant effect on extraction of gold.The extraction of the mixture solution of metal cyanide ...
Gold(I) could be extracted directly from alkaline cyanide solution efficiently using an organic phase composed of MSO, TBP and n-octanol, and efficiently stripped by Na 2 S 2 O 3 aqueous solution. Further study may fulfill its potential application in the extraction and separation of gold.
A PROPOSED SOLVENT-EXTRACTION ROUTE FOR THE TREATMENT OF COPPER CYANIDE SOLUTIONS PRODUCED IN LEACHING OF GOLD ORES MR Davis Lycopodium Pty Ltd KC Sole Mintek J M W Mackenzie M J Virnig Henkel Australia Pty Ltd Henkel Corporation, MID TABLE OF CONTENTS ABSTRACT 1 1.0 INTRODUCTION 2 2.0 COPPER LEACHING IN CYANIDE SOLUTIONS 4
Solvent extraction of gold from alkaline cyanide solution was limited due to the lack of a selective extractant. Recent developments in solvent extraction using modified amines and alkyl phosphorus esters have been reported to provide for selective gold extraction from alkaline cyanide solution [5].Patented Gold Extraction/Recovery Methods
Hydrophobic ionic liquids as novel extractants for gold (I) recovery from alkaline cyanide solutions. Journal of Chemical Technology and Biotechnology, 90(6) (2015) 1102-1109. [13] Wang, S., Shi, D., Yang, R., Xu, Y., Guo, H., Yang, X *. Solvent extraction of phenol from aqueous solution with benzyl 2‐ethylhexyl sulfoxide as a novel extractant.
MIBK affinity for the gold ions and complexes found in alkaline solution is limited, so the method requires that alkaline solutions be acidified in a hood prior to the addition of MIBK for extraction and separation. The second method uses a solution of DIBK and trialkyl ammonium chloride (Aliquat 336) to extract solutions over pH ranges of 1-l2.5.
Solvent extraction of KAu(CN) 2 from alkaline cyanide solution by using the pre‐acidified tertiary amine, tri‐n‐octylamine(TOA) as extractant with the addition of tri‐n‐butyl phosphate (TBP) as a synergist has been studied. The influence of several variables such as the molar ratio of TOA to KAu(CN) 2 (n r), the volume percentage of TBP (ϕ TBP), the phase ratio of the organic phase ...
OSTI.GOV Conference: Selective solvation extraction of gold from alkaline cyanide solution by alkyl phosphorus esters
The direct extraction of gold from alkaline cyanide solution with dibutyl sulfoxide and n-octanol diluted in kerosene was investigated. It has been indicated that the gold extraction percentage increases by increasing dibutyl sulfoxide concentration, n-octanol concentration, and organic-to-aqueous (O/A) phase ratio, but decreases with the increase of initial gold concentration and equilibrium ...
SOLVENT EXTRACTION REAGENTS FOR GOLD RECOVERY FROM ALKALINE CYANIDE SOLUTIONS J. D. Miller and C. A. Garcia Department of Metallurgical Engineering University of Utah Salt Lake City UT 84112, USA Abstract Three different solvent extraction systems for the recovery of gold from alkaline cyanide solutions are reviewed.
In this work the extraction of gold(I) from alkaline cyanide solution using DBC with n-octanol was studied. Several factors affecting the percentage extraction of gold(I), including DBC concentration, diluent concentration, equilibrium time, phase ratio, pH and gold concentration in aqueous phase, were investigated.
extract gold directly from alkaline cyanide solutions, including amines, modified amines, guanidine, substituted guanidine, sulfoxide category materials as well as crown ethers [11-16]. In the present work, we have tried to extract gold directly from alkaline cyanide solution using . a . synthesized sulfoxide MSO as extractant with addition of ...
Gold Extraction Plant By Cynide . The process of gold extraction using cyanide involves a weak cyanide solution being added to the ore causing the gold to dissolve into the solution and thus forming a gold cyanide complex The gold is then recovered from this gold cyanide solution by using various methods such as carbon adsorption ionexchange resin or zinc dust precipitation
Solvent Extraction of Gold(Ⅰ) from Alkaline Cyanide Solution with Synthesized Sulfoxide MSO under Assistance of TBP PAN Lu, GU Guobang Solvent Extraction Research and Development, Japan 19(0), 117-125, 2012
Solvent extraction of gold from alkaline cyanide solution was limited due to the lack of a selective extractant. Recent developments in solvent extraction using modified amines and alkyl phosphorus esters have been reported to provide for selective gold extraction from alkaline cyanide solution [5].
Bis-cyclohexyl-bis-(2-ethylhexyl)guanidine for selective extraction of aurum from aqueous, alkaline or cyanide solutions Download PDF Info ... extraction aqueous solution gold Prior art date Application number SU915001511A Other languages Russian (ru) Inventor
Under these circumstances, gold can be extracted at about pH 10, commensurate with the pH of cyanide leach liquors. The selectivity of the amines and amine/modifier combinations for Au(CN) − 2 over other metal-cyanide complexes is discussed. Potential applications for the solvent extraction of gold from cyanide solutions are also discussed.
monly in leach liquors used for the extraction of gold from ores. This process is normally performed at about pH 10 to 11, so that it would be convenient if the gold(I) cyanide could be extracted directly from the alkaline medium into an organic solvent. Flett (8) studied briefly the solvent extraction of gold(I) cyanide by amines and ...
In this study, a polymer inclusion membrane (PIM) was used for the extraction and recovery of gold(I) from alkaline cyanide solutions in a prompt, concise manner. Compared with traditional solvent extraction technology, PIM is especially suitable for the separation of low concentration gold(I). A PIM containing [A336][SCN] as the carrier, polyvinylidene difluoride as a polymer matrix, and 2 ...
Solvent extraction of cadmium from alkaline cyanide solutions with quaternary amines. Moore FL. Quaternary amines are unique in their ability to extract metal cyanides from highly alkaline solutions. Cadmium cyanide extracts essentially quantitatively at both the subnanogram and macro levels. Regeneration of the amine solvent is achieved by ...
Abstract. 198Au(TDMBA),、、、KAu(CN)2nr,、.,10%, ...
Solvent extraction of gold(I) dicyanide anion from alkaline gold(I) cyanide solution using unusually basic amine extractants was conducted. 1,5,9-Triazacyclododecane (4) is known as an unusually ...
Continuous laboratory solvent extraction of gold from cyanide solutions has been investigated by using LIX 79 guanidine-based extractant. Different variables that affected the extraction included aqueous pH, extractant concentration and modifier concentration.
Abstract The extraction of gold(I) from aurocyanide solutions has been studied by means of the synergic mixture of the primary amine Primene JMT and the phosphine oxide Cyanex 921. Different variables that could affect the solvent extraction system were evaluated: equilibration time, temperature, aqueous pH, metal concentration, extractant mixture concentration, organic phase diluent and ...
The closest analogue of the essential features and purpose is disclosed in RU 2046628 C1 (IPC SW 3/00, publ. 27.10.1995) the method of extraction of gold from alkaline cyanide solutions by contacting the aqueous solution of cyanide of gold from anion exchange resin on the basis of polyguanidine.
The solvent extraction of gold and the structure of the organic phase were studied by labelled 198Au, 31P NMR and FTIR spectroscopy. The results show that the water content increased with the increase of gold contents in the organic phase. The P=O stretching decreases, while the 31P signal shifts to upfield.
Miller, J.D. et al. (1987), Selective Solvation Extraction of Gold from Alkaline Cyanide Solution by Alkyl Phosphorus Esters, Separation Science & Technology, 22(2&3):487-502. Mooiman, M.B. & Miller, J.D. (1991), The Chemistry of Gold Solvent Extraction from Alkaline Cyanide Solution by Solvating Extractants, Hydrometallurgy, 27:29-46.
Although ionic liquids (ILs) as green solvents have become a focus of research in the field of metal ions separation, little attention has been paid to gold(I) recovery from alkaline cyanide solutions using ILs as extractants. Therefore, this work explores gold(I) extraction using hydrophobic imidazolium-based ionic liquids. RESULTS
This paper explores the solvent extraction of KAu(CN) 2 from alkaline cyanide solutions using quaternary ammonium cetylpyridinium bromide (CPB) as an extractant with the addition of tributylphosphate (TBP) as a modifier. It also investigates the influence of several variables on gold extraction, including the molar ratio (β) of CPB to Au(I), the volume percentage of TBP (φ TBP), NaCl ...
Continuous laboratory solvent extraction of gold from cyanide solutions has been investigated by using LIX 79 guanidine‐based extractant. Different variables that affected the extraction included aqueous pH, extractant concentration and modifier concentration. Extraction isotherms of the aurocyanide complex with respect to the other cyanoanions were compared, and the following order of ...
The solvent extraction of gold from alkaline cyanide solution by primary amine N1923 and Tri-butylphosphate (TBP) was described by Au-198 radioactive tracer method. The influence of several variables such as acidification percentage, pH of raffinate solution, concentration of N1923, volume percentage of TBP were discussed.
A technique for extracting gold values from an aqueous system containing gold cyanide anions by contact with a strong solvating extractant under basic conditions is disclosed. Useful extractants include organic phosphorus oxides and sulfur oxides. US4540435A - Solvent extraction of gold and silver anions under alkaline conditions - Google ...